Last edited by Gogore
Thursday, August 6, 2020 | History

3 edition of Transition metal hydrides found in the catalog.

Transition metal hydrides

Transition metal hydrides

  • 165 Want to read
  • 13 Currently reading

Published by VCH Pub. in New York, N.Y .
Written in English

    Subjects:
  • Transition metal hydrides.

  • Edition Notes

    Includes bibliographical references and index.

    Statementedited by A. Dedieu.
    ContributionsDedieu, A.
    Classifications
    LC ClassificationsQD172.T6 T733 1992
    The Physical Object
    Paginationx, 399 p. :
    Number of Pages399
    ID Numbers
    Open LibraryOL1549570M
    ISBN 100895737817
    LC Control Number91029176

    Transition metal hydrides. Dedieu Buy from $ Metal Hydrides. Gust Bambakidis Buy from $ Shape Memory Materials. K Otsuka (Editor), C M Wayman (Editor) Buy from $ Catalytic transition metal D. W. Slocum, William R. Moser Buy from $ Maintenance-free Batteries: Dietrich Berndt Buy from $ Maintenance-Free.   Abstract. This chapter discusses about metal hydride technologies for on-board reversible hydrogen storage applications. The metal hydrides such as intermetallic alloys and solid solutions have interstitial vacancies where atomic hydrogen is absorbed via an exothermic reaction; however, by endothermic path, the metal hydride desorbs the hydrogen reversibly at Cited by: 6.

    Metal hydrides can store more hydrogen per unit volume than normal high pressure or cryogenic techniques. Little energy is required to store the hydrogen in the hydride, and high stability at room temperature ensures low losses over long storage periods. Safety features of metal hydride storage are favorable. @article{osti_, title = {Study of the bonding in transition metal carbonyl hydrides}, author = {Chen, H.W. and Jolly, W.L. and Kopf, J. and Lee, T.H.}, abstractNote = {The metal 2p/sub 3/2/, carbon ls, and oxygen ls binding energies of the gaseous molecules Co/sub 2/(CO)/sub 8/, HCo(CO)/sub 4/, Fe(CO)/sub 5/, H/sub 2/Fe(CO)/sub 4/, Mn.

    Towards multiscale simulations of carbon nanotube growth process: A density functional theory study of transition metal hydrides Satyender Goel *, Author: Satyender Goel, Artëm E. Masunov. Transition-metal hydrides have been developed as alternatives to tin hydrides. The weakness of the transition-metal-hydrogen bond (as weak as 55 kcal/mol) allows a different approach to generating radicals: direct transfer of H- from M-H to an olefin.


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Transition metal hydrides Download PDF EPUB FB2

Transition Metal Hydrides 1st Edition by A. Dedieu (Editor) ISBN Author: A. Dedieu. Metal Hydrides focuses on the theories of hydride formation as well as on experimental procedures involved in the formation of hydrides, the reactions that occur between hydrides and other media, and the physical and mechanical properties of the several classes of hydrides.

The use of metal hydrides in the control of neutron energies is. Classical transition metal hydride feature a single bond between the hydrogen centre and the transition metal.

Some transition metal hydrides are acidic, e.g., HCo(CO) 4 and H 2 Fe(CO) 4. The anions [ReH 9] 2− and [FeH 6] 4− are examples from the growing collection of known molecular homoleptic metal hydrides. As pseudohalides, hydride. Not only the metal hydrides are needed as synthetic reagents for preparing the transition metal organometallic compounds but they also are required for important hydride insertion steps in many catalytic processes.

The first transition metal hydride compound was reported by W. Heiber in when he synthesized Fe(CO) 4 H 2. The first part of the book focuses on the chemistry and catalysis of transition metal hydrides.

Another block of chapters illustrates the most recent advances in the application of instrumental techniques to the study of the properties and reactivity of hydride compounds.

anionic metal hydrides by Darensbourg and Ash in and one on early transition-metal hydrides by Hoskin and Stephan in ,12 while two reviews of dihydrogen complexes,13,14 a review of their applications in catalysis,15 a review on the computational analysis of polyhydrides,16 a review of the M−H.

Transition metal σ−bonded organometallic compounds like the metal alkyls, aryls and the hydrides derivatives are by for the most common organometallic species encountered in the world of chemistry.

This work surveys recent advances made in the scientific understanding of the structure and reactivity properties of transition metal hydrides at both the theoretical and the experimental level.

Book\/a> ; \u00A0\u00A0\u00A0\n library:oclcnum\/a> \" # Hydrures des m\u00E9taux de transition\/span>\n \u00A0\u00A0\u00A0\n schema. COVID Resources. Reliable information about the coronavirus (COVID) is available from the World Health Organization (current situation, international travel).Numerous and frequently-updated resource results are available from this ’s WebJunction has pulled together information and resources to assist library staff as they consider how to handle.

However, several books, all with the title Transition Metal Hydrides, have been published whose chapters allow one to track the growth of this subject since it first attracted widespread attention in the book edited by Muetterties () emphasized the synthesis and stereochemistry of hydride complexes.

The volume edited by Bau (Advances in Chemistry #, ) Cited by:   The use of metal hydrides in the control of neutron energies is discussed, as are many other immediate or potential uses, e.g., in the production of high-purity hydrogen and in powder metallurgy.

It is hoped that this book will serve as a valuable reference to students, research professors, and industrial researchers in metal hydrides and in Book Edition: 1.

Catalytic Transition Metal Hydrides (Annals of the New York Academy of Sciences) by D. Slocum (Editor), William R. Moser (Editor) ISBN ISBN Why is ISBN important. ISBN. This bar-code number lets you verify that you're getting exactly the right version or edition of a book.

Transition metal hydrides play a critical role in stoichiometric and catalytic transformations. Knowledge of free energies for cleaving metal hydride bonds enables the prediction of chemical. Pour télécharger un livre numérique Kindle/PDF/ePub Transition Metal Hydrides, appuyez sur Extrait gratuit ou Acheter.

Pour obtenir de plus amples informations sur un livre numérique, appuyez sur sa couverture. Télécharger Transition Metal Hydrides vos Ebook Gratuit français Gratuitement en format Epub, PDF, Kindle et utiliser votre lisseuse préférée pour les lire.

Not Available Book Review: Transition Metal Hydrides. edited by A. Dedieu; VCH, Weinheim/New York/Basel/Cambridge,pp. x+, price £Author: S. Agostic alkyls having interactions between the ligand CH bonds and the metal provide a pathway for beta elimination, one of the main decomposition routes.

Formation pathways include oxidative addition and insertion. Related ligands, such as alkoxides. Transition metal hydrides: a symposium sponsored by the ACS Division of Inorganic Chemistry at the 2nd Joint Conference of the Chemical Institute of Canada and the American Chemical Society, Montreal, May June 2, Pages:   Open Library is an open, editable library catalog, building towards a web page for every book ever published.

Transition Metal Hydrides by A. Dedieu; 2 editions; First published in Transition Metal Hydrides | Open Library. The chemical shift range for hydrides is approximately +25 to ppm. The downfield shifts are most common in d 0, d 10 and early transition metal cases whereas those with other d n counts and late transition metals tend to be upfield of zero.

Coupling to other spin active nuclei such as 31 P often makes structural assignments unambiguous. Considering the scope of complex transition metal hydrides that have been characterised since the s [1, 2], there is a distinct absence of Na-based complex transition metal.

3 Metal Alkyls, Aryls, and Hydrides and Related σ-Bonded Ligands 53 Transition Metal Alkyls and Aryls, 53 Related σ-Bonded Ligands, 68 Metal Hydride Complexes, 72 σ Complexes, 75 Bond Strengths for Classical σ-Bonding Ligands, 79 4 Carbonyls, Phosphine Complexes, and Ligand Substitution Reactions 87File Size: 7MB.This Feature Article intends to provide an overview of a variety of catalytic isomerization reactions that have been performed using well-defined transition metal hydride precatalysts.

A particular emphasis is placed on the underlying mechanistic features of the transformations discussed. These have been catCited by: MgH 2 marks the transition between these predominantly ionic hydrides and the covalent hydrides of the other elements in the first two periods. Examples for high temperature hydrides releasing the hydrogen at pressures of 1 bar at extremely high temperatures (T > ºC) are ZrH 2 and LaH 2 (Dornheim & Klassen, ).Cited by: